Hazards of transportation and transfer of ethanol and. Safety data sheet gel hand sanitizer 2 8 chemical name casno. Hazards of transportation and transfer of ethanol and ethanol. Sigmaaldrich e7023 page 1 of 7 sigmaaldrich material safety data sheet version 4. Hazards identification emergency overview routes of entry for methanol are primarily absorption through the skin, eye contact, inhalation, or ingestion. Other safety plans common to ethanol plant operations. Dermal ld50 based on ate data, the classification criteria are not met. Water spray may be used to knock down or divert vapour clouds. Accidental release measures keep unnecessary personnel away. Because of its incredible versatility, ethanol mixes very well with other solvents and water, as well as chlorides and hydrocarbons. As with most organic solids, fire is possible at elevated temperatures special remarks on explosion hazards. Bp28184, bp2818100, bp2818500 casno 64175 synonyms ethyl alcohol.
Wear appropriate protective equipment and clothing during cleanup. Ethanol undenatured classified as hazardous disposal. Exposure guidelines no exposure standards allocated. Methanol safety data sheet according to federal register vol. Do not handle until all safety precautions have been read and understood. Apr 21, 2014 because of its incredible versatility, ethanol mixes very well with other solvents and water, as well as chlorides and hydrocarbons. For small fires, use dry chemical, carbon dioxide, water spray or alcoholresistant foam. Safety data sheet ethanol page 3 of 3 butane 106978 0. Toxicity read msds storage tank fire at an ethanol plant ethanol tank explosion tank roof blew off and fell on top of fire. Many gases are heavier than air and will spread along ground and collect in low or confined areas sewers, basements, tanks. Gasvapor flammable with air within explosion limits. Be aware of static electricity generation when handling material. This fact sheet presents general guidelines regarding the hazards of transporting ethanol and ethanol blended fuels via rail and trucks to promote regulatory compliance and best practices for their safe transport. Industrial exposures are primarily vapor exposures and skin contact.
Solvent vapours may form explosive mixtures with air. For large fires, use water spray, fog, or alcoholresistant foam. Ethanol is rapidly oxidized in the body to acetaldehyde, then to acetate, and finally to carbon dioxide and. Ethanol is a flammable liquid whose vapours can form ignitable and explosive mixtures with air at normal room temperatures. Ingestion may cause mucous membrane and gastrointestinal irritation and nervous system depression with symptoms of headache, dizziness, nausea, vomiting, weakness, fatigue, restlessness, confusion, drunken behavior.
Hazards of transportation and transfer of ethanol and ethanolblended fuels. Ethanol, 60%, technical revision date 29jan2018 11. Safety data sheet of6 infosafe noz1ch89 issue date. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number. Safety data sheet denatured ethanol sinclair oil corporation. Hazards identification potential acute health effects.
This fact sheet presents general guidelines regarding the hazards of transporting ethanol and ethanolblended fuels via rail and trucks to promote regulatory compliance and best practices for their safe transport. Skin contact wash off immediately with plenty of water for at least 15 minutes. Personal evacuate the area of all nonessential personnel. Ethanol, anhydrous histological revision date 18jan2018 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Extreme exposure such as intentional inhalation may cause unconsciousness, asphyxiation and death. Dot un3475 ethanol and gasoline mixture 3 pg ii no tdg un3475 ethanol and gasoline mixture 3 pg ii no imdg un3475 ethanol and gasoline mixture 3 pg ii no iata un3475 ethanol and gasoline mixture 3 pg ii no transport in bulk according to annex ii of marpol 7378 and the ibc code. Ethanol is rapidly oxidized in the body to acetaldehyde, then to. Materials safety data sheet msds ethanol c 2 h 5 oh msds number ncpp1 version number version 2. Page 3 of 7 spray until well after the fire is out. Vapors may travel considerable distance to a source of ignition and flash. Hazards identification ghs classification of substance in accordance to regulation ec no. Identification product name ethanol, 60%, technical cat. Material safety data sheet ethanol sda1, anhydrous msds. Product name molecular biology grade ethanol cat no.
Specific methods use standard firefighting procedures and consider the hazards of other involved materials. Ethanol production and safetyethanol production and safety. Page 1 of 8 msds monoethanolamine material safety data sheet msds monoethanolamine 1. Precautionary statements prevention obtain special instructions before use. Use proper personal protective equipment as indicated in section 8.
Relevant identified uses of the substance or mixture and uses advised against. Acgih threshold limit values material type value 200p ethanol stel ppm us. This chemical is considered hazardous by the 2012 osha hazard communication standard. Eye contact may cause irritation with redness, tearing and pain. Group 1 by iarc, though ethanol itself has not been classified by this agency. Identification product identifier 200p ethanol other means of identification. Special hazards arising from the substance or mixture.
Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Safety data sheet ethanol page 2 of 2 may cause drowsiness or dizziness. May cause chemica l conjunctivitis and corneal damage. Special hazards arising from the substance or mixture ethanol 99,8% page 2 of 7. Toxicological information acute toxicity product information oral ld50 based on ate data, the classification criteria are not met. Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust explosion hazard. Page 1 of 7 msds triethanolamine material safety data sheet msds triethanolamine 1. No other components are listed as carcinogens by iarc, us osha or ntp. The north american fire arts association was established in 2002 to provide resources to fire artists, to aggressively create and maintain a set of nationally recognized self governed safety standards regarding fire art and to establish fire art as a recognized genre of. Safety data sheet quaternary disinfectant cleaner 9496 5 cause ignition of organic vapors. Chemical product and company identification product name. Thus, an aqueous mixture containing 30% ethanol can produce a flammable mixture of.
Absolute ethanol recommended use laboratory chemicals. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have collectively been termed the fetal alcohol syndrome. Identification of the substancemixture and of the companyundertaking date issued 26. Pocket guide to chemical hazards material type value 200p ethanol twa 1900 mgm3 ppm biological limit values no biological exposure limits noted for the ingredients. Ethanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. Ethanol ppm ppm twa ppm twa ppm twa 1900 mgm3 twa 1900 mgm3 twa 1900 mgm3 twa 3300 ppm idlh. Identification product identifier spray clean hd other means of identification sds number 576n8a product code hil01820 recommended use general cleaner for labeled use only do not use on or near uncured painted surfaces. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations that have collecetively been termed the fetal alcohol syndrome. Acgih threshold limit values components type value ethanol cas 64175 stel ppm us. Material safety data sheet industrial denatured alcohol msds name. Pocket guide to chemical hazards components type value ethanol cas 64175 twa 1900 mgm3 ppm biological limit values no biological exposure limits noted for the ingredients. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Initial symptoms from ingestion or inhalation may be only mild intoxication, but may become severe after 1218 hours. In serious cases absorption of methanol in the body may lead to damage to the eyesight. Very hazardous in case of eye contact irritant, of ingestion. Denatured alcohol safety data sheet supercedes revision. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. Eliminate all ignition sources no smoking, flares, sparks, or flames in immediate area. Section 3 hazards identification emergency overview highly flammable. For small fires, use dry chemical, carbon dioxide, water spray or alcohol resistant foam. Ethanol production and safetyethanol production and safety wei liao, chris saffron. Identification product name molecular biology grade ethanol cat no.
Section 6 accidental release measures general information. Chronic ingestion of ethanol has been associated with an increased incidence. No action shall be taken involving any personal risk or without suitable training. Use proper bonding and grounding when transferring material. Hazards of transportation and transfer of ethanol and ethanol blended fuels. Ethanol ch3ch2oh or c2h6o cid 702 structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities. Being this versatile, ethanol is used for a great many things but it can also be quite dangerous. Safety data sheet according to 29cfr19101200 and ghs rev. A vapor suppressing foam may be used to reduce vapors. Denatured ethanol april 16, 2015 page 5 of 7 eye contact. Materials safety data sheet msds date issued rd3 may 2012. Versatile, common and potentially dangerous msdsonline. Physical hazards flammable aerosol category 1 health hazards. P270 do not eat, drink or smoke when using this product.
Methanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory animals. Uses advised against not for food, drug, pesticide or biocidal product use. Product name ethanol, anhydrous histological cat no. Note that contaminated clothing may be a fire hazard.
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